Product ID:839 6210,KODAK FIXER,SINGLE-USE CHEMISTRY KIT,PROCESS E-6
MSDS Date:02/01/1999
FSC:6750
NIIN:01-301-8779
Status Code:A
Kit Part:Y
MSDS Number: CKVZZ

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

ACGIH TLV: NOT PROVIDED

WATER

CAS: 7732-18-5

RTECS: ZC0110000

SODIUM BISULFITE

CAS: 7631-90-5

RTECS: VZ2000000

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM SULFITE

CAS: 10196-04-0

ACGIH TLV: NOT PROVIDED

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

ACGIH TLV: NOT PROVIDED

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL
HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL H AS A LOW POTENTIAL
TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN
SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF
SWALLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUA LS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. INGESTION: MAY CAUSE IRRITATION OF THE
GASTROINTESTINAL TRACT IF SWALLOWED.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK
1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCO NSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:FLOOD WITH WATER.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.

Spill Release Procedures:COLLECT IN A NONCOMBUSTIBLE CONTAINER FOR
PROMPT DISPOSAL. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR C HEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. DO
NOT STORE/SHIP TOGETHER WITH COMBUSTIBLE MATERIALS. STORE IN
ORIGINAL CONTAINER. KEEP FROM CONTACT WI TH OXIDIZING MATERIALS,
HIGHLY OXYGENATED/HALOGENATED SOLVENTS, ORGANIC COMPOUNDS/ AQUEOUS
AMMONIA.
Other Precautions:AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED
CONTACT WITH SKIN. AVOID BREATHING MIST OR VAPOR. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. REMOVE AND WASH
CONTAMINATED CLOTHING PROMPTLY. KEEP AWAY FROM COMBUSTIBLE
MATERIAL.

Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT: IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT
PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT
ESTABLISHED.

HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.36
pH:6.2
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, ODORLESS LIQUID.
Percent Volatiles by Volume:35-40 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS, STRONG ACIDS, BASES,
STRONG OXIDIZING AGENTS, SODIUM HYPOCHLORITE (BLEACH). CONTACT WITH
BASE LIBERATES SODIUM HYPOCHLORITE (BLEACH).
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:AMMONIA, CHLORAMINE. CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO
BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY
TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED,
SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE GAS IS
IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL H AS A LOW POTENTIAL
TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN
SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF
SWALLOWED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS MATERIAL, HAS NOT BEEN TESTED FOR ENVIRONMENTAL
EFFECTS. IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A
MODERATE BIOCHEMICAL OXYGEN DEMAND AND MAY CAUSE OXYGEN DEPLETION
IN AQUEOUS SYSTEMS, A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, A
LOW POTENTIAL TO AFFECT SECONDARY WASTE TREATMENT MICROBIAL
METABOLISM, A MODERATE POTENTIAL TO AFFECT THE GERMINATION AND/OR
EARLY GROWTH OF SOME PLANTS, A LOW POTENTIAL TO PERSIST IN THE
ENVIRONMENT, A LOW POTENTIAL TO BIOCONCENTRATE. AFTER DILUTION WITH
A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT,
THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL
EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: AMMONIUM THIOSULFATE; AMMONI UM SULFITE, AS SOURCES OF
AQUEOUS AMMONIA.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE